Studies on Time-Temperature Curve for Emulsion Polymerization of Vinyl Monomer
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چکیده
منابع مشابه
A Kinetic Study of the Emulsion Polymerization of Vinyl Acetate
This report deals with the chemically and the radiation-initiated emulsion polymerization of vinyl acetate. In experiments with potassium persulphate as initiator and sodium lauryl sulphate (SLS) as emulsifier the rate of polymerization is approximately proportional to the square root of initiator concentration and to the 0.25 power of the number of particles. The number of particles is proport...
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a mixture of sodium lauryl sulfate (sls) as ionic emulsifer and stearyl alcohol as non-ionic emulsifer was employed in a vinyl chloride emulsion polymerization reaction to study the infuence of various interactive parameters involved in the reaction system. it was found that the particle size was dependent on the amount and type of emulsifer. the average particle size of polyv...
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Polybutadiene nanoparticles were synthesized via batch emulsion polymerization of butadiene in the presence of potassium persulfate, disproportionate rosinate potassium cation and t-dodecyl mercaptane as initiator, emulsifier and chain transfer agent, respectively. Polymerization reaction was performed at different temperatures (60, 70 and 80 °C). Conversion was measured at the various time int...
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In this study, the emulsion homopolymerization system containing vinyl acetate, potassium persulfate, a new cationic polymeric surfactant and water was studied by the applying semi-continuous emulsion polymerization process. The effects of new polymeric emulsifier on the physicochemical properties of obtained vinyl acetate latexes were investigated depending on vinyl acetate percentage in the p...
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Dispersion of liquid–liquid systems is commonly applied in industrial processes such as extraction, suspension, and emulsion polymerization. This article describes the influence of the quality of emulsification on the course and outcome of a batch-emulsion polymerization of styrene and vinyl acetate. From visualization experiments and polymerizations in combination with reaction calorimetric st...
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ژورنال
عنوان ژورنال: Kobunshi Kagaku
سال: 1968
ISSN: 1884-8079,0023-2556
DOI: 10.1295/koron1944.25.742